Guided acoustic waves Acoustic as catalysts for the energy turnaround
Funding programme: BMBF “Förderinitiative Energiespeicher” (Energy Storage Funding Initiative)
Energy storage systems must meet constantly increasing requirements with regard to charging duration, durability and functional efficiency with rapidly changing energy requirements. In view of the growing importance of regenerative forms of energy in electricity generation, the fluctuation of charging and discharging processes and thus the desire for shorter charging times will increase. The re-availability and ageing behaviour of the energy storage device after a power consumption is mainly determined by its ability to absorb high quantities of electricity reversibly in the shortest possible time. The chemical reactions that take place when energy is stored in batteries, however, depend very much on the transport speed at the electrodes; here too, the electrochemical double layer slows down the transport of the charge carriers. As part of a research project funded by the BMBF (Förderinitiative Energiespeicher), ISAT is investigating how the electrochemical transport inhibitors at the electrodes of test batteries can be eliminated by guided acoustic waves. The aim of the project is the development of an additional acoustic component (“charging time booster”) with which rechargeable batteries can be equipped or retrofitted.
In doing so, one takes advantage of the fact that guided acoustic waves excited on electrodes can have a direct effect on the electrochemical boundary layer. This interface consists of adsorbed anions and solvated ions. As soon as the electrochemical double layer has formed, the exchange of charge carriers between electrolyte and electrode can only take place by charge carrier diffusion. This boundary layer inhibits the transport of charge carriers to the electrode and thus slows down the electrochemical reaction. The excitation of acoustic interfacial waves on the electrode can succeed in mixing or breaking up the electrochemical double layer. For this purpose, non-decoupling evanescent interfacial waves are preferably generated which remain bound to the electrode/electrolyte interface. This makes it possible for the acoustic wave to propagate completely over the electrode. In the electrochemical boundary layer near the electrode, eddy currents are generated in this way, which thins out the boundary layer and accelerates the charge carrier transport.
Simulation of the acoustic pressure field generated by interfacial waves at the interface electrode/electrolyte
Left: Electrochemical boundary layer (blue) near the electrode. Right: Acoustic vortex flow generated by interfacial waves in the electrochemical interface.
The investigations were initially carried out on commercially available lead sulphuric acid batteries, as these are currently still very frequently used as decentralised energy storage systems. In addition, they have a comparatively simple structure and the chemical processes taking place in them have been sufficiently understood. Lead batteries consist of negative lead and positive lead oxide plates which are separated from each other by separators. 37% sulphuric acid acts as electrolyte. The electrodes consist of a grid. In order to systematically investigate the influence of interfacial waves on the charging time of lead-acid batteries, a semi-automated test stand was set up to carry out defined charging and discharging cycles with and without acoustic coupling. The results obtained with this test stand show that surface waves can also be excited on the lead electrodes – despite the grid-shaped electrodes, the surface waves propagate over the entire electrode, which can be measured using a laser doubler vibrometer.
If one compares the charge curves of a lead acid battery without excitation of boundary surface waves on the electrodes with experiments in which boundary surface waves are excited, a visible influence on the charge curve can be determined. So far, charging times can be reduced by up to 10%. It is conceivable that the charging time could be reduced by around 25% by further optimization steps. ISAT is also currently working on the construction and commissioning of a redox flow cell and would like to transfer the knowledge gained to date to this innovative energy storage device of the future